It expands on the foundation acquired in chemistry courses and enables students to understand the mechanisms as they come across them in your classroom or laboratory.Organic Reaction Mechanisms provides extensive coverage of various organic reaction and rearrangements with emphasis on their applications in syntheses. The authors discuss reaction pathways, such as substitutions, additions, eliminations, oxidations, reductions, aromatic substitutions, aliphatic nucleophilic substitution, and electrophilic substitutions with numerous reaction equations to show the mechanism. The text also details the various reaction intermediates, including carbocations, carbanions, free radicals, carbenes, nitrines, benzynes, arynes, ylides, and enamines.Furthermore, the reagents are surveyed throughout the text, and correlation tables are provided to aid in identifying which oxidation/reduction agents to use for oxidizing/reducing various types of compounds. The applications of organic reagents are illustrated with examples and problems at the end of each chapter, which also serve to review the mechanisms learned and topics discussed. A comprehensive discussion on organic reactions, Organic Reaction Mechanisms will benefit advanced undergraduate and graduate chemistry students in their understanding and application of organic syntheses.

    The atomic bombs that came out of it brought an end to the war in the Pacific, but at a heavy loss of life in Japan and the opening of a Pandora's box that has tested international relations.This book traces the history of the Manhattan Project, from the first glimmerings of the possibility of such a catastrophic weapon to the aftermath of the bombings of Hiroshima and Nagasaki. It profiles the architects of the bomb and how they tried to reconcile their personal feelings with their ambition as scientists. It looks at the role of the politicians and it includes first-hand accounts of those who experienced the effects of the bombings.

    No one seemed able to agree on a cause. (Dark matter? Tensor–vector–scalar gravity? Collisions with gravitons?) What did seem clear to those who became obsessed with it was that the Pioneer Anomaly had the potential to upend Einstein and Newton—to change everything we know about the universe.With riveting prose and the precision of an expert, Konstantin Kakaes gives us a scientific police procedural, tracking the steps of those who sought to unravel this high-stakes enigma. His thrilling account draws on extensive interviews and archival research, following the story from the Anomaly’s initial discovery, through decades of tireless investigation, to its ultimate conclusion. “The Pioneer Detectives” is a definitive account not just of the Pioneer Anomaly but of how scientific knowledge gets made and unmade, with scientists sometimes putting their livelihoods on the line in pursuit of cosmic truth. Perfect for fans of John McPhee, Thomas Kuhn, and Ed McBain, this is also an immensely enjoyable story accessible to anyone who loves brilliant, fascinating long-form journalism.* * * ABOUT THE AUTHOR: Konstantin Kakaes is a Bernard L. Schwartz fellow at the New America Foundation, writing about science and technology, and is the former Mexico City bureau chief for The Economist. His work has been published in The Wall Street Journal, Foreign Policy, and The Washington Post and appears frequently in Slate. Before becoming a journalist, he studied physics at Harvard University.

    Tesla's rare article, 'The Problem of Increasing Human Energy with Special Reference to the Harnessing of the Sun's Energy' is included. This lengthy article was originally publishing in the June 1900 issue of The Century Illustrated Monthly Magazine and it was the outline for Tesla's master blueprint for the world. Tesla's fantastic vision of the future, including wireless power, anti-gravity, free energy and highly advanced solar power. Also included are some of the papers, patents and material collected on Tesla at the Colorado Spring Tesla Symposiums. Tesla was the inventor of the radio before Marconi, and when he demonstrated wireless remote control to the US Navy in the late 1890s, they replied that it was too advanced! Tesla was an eccentric visionary and probably the greatest inventor who ever lived. His basic inventions power the world of today. What was his vision of tomorrow? Find out in The Tesla Papers.

    

    To contain secrets, American and Soviet leaders created plutopias--communities of nuclear families living in highly-subsidized, limited-access atomic cities. Fully employed and medically monitored, the residents of Richland and Ozersk enjoyed all the pleasures of consumer society, while nearby, migrants, prisoners, and soldiers were banned from plutopia--they lived in temporary "staging grounds" and often performed the most dangerous work at the plant. Brown shows that the plants' segregation of permanent and temporary workers and of nuclear and non-nuclear zones created a bubble of immunity, where dumps and accidents were glossed over and plant managers freely embezzled and polluted. In four decades, the Hanford plant near Richland and the Maiak plant near Ozersk each issued at least 200 million curies of radioactive isotopes into the surrounding environment--equaling four Chernobyls--laying waste to hundreds of square miles and contaminating rivers, fields, forests, and food supplies. Because of the decades of secrecy, downwind and downriver neighbors of the plutonium plants had difficulty proving what they suspected, that the rash of illnesses, cancers, and birth defects in their communities were caused by the plants' radioactive emissions. Plutopia was successful because in its zoned-off isolation it appeared to deliver the promises of the American dream and Soviet communism; in reality, it concealed disasters that remain highly unstable and threatening today.An untold and profoundly important piece of Cold War history, Plutopia invites readers to consider the nuclear footprint left by the arms race and the enormous price of paying for it.

    No previous book, however, has explored the regime's effect on people's personal lives, what one historian called "the Stalinism that entered into all of us." Now, drawing on a huge collection of newly discovered documents, The Whisperers reveals for the first time the inner world of ordinary Soviet citizens as they struggled to survive amidst the mistrust, fear, compromises, and betrayals that pervaded their existence.Moving from the Revolution of 1917 to the death of Stalin and beyond, Orlando Figes re-creates the moral maze in which Russians found themselves, where one wrong turn could destroy a family, or perversely, end up saving it. He brings us inside cramped communal apartments, where minor squabbles could lead to fatal denunciations; he examines the Communist faithful, who often rationalized even their own arrest as a case of mistaken identity; and he casts a humanizing light on informers, demonstrating how, in a repressive system, anyone could easily become a collaborator.A vast panoramic portrait of a society in which everyone spoke in whispers--whether to protect their families and friends, or to inform upon them--The Whisperers is a gripping account of lives lived in impossible times.

    David Horowitz’s classic Why Israel is the Victim, updated by the author, sets the record straight about the basic truths of the Middle East conflict. In addition to restoring the authentic history of the region – a history of obsessive aggression first by Arab countries determined to physically annihilate the Jewish State and later by terror groups determined to destroy its will to survive and right to exist—this booklet brings the story up to date by showing the systematic way in which Hamas and Hezbollah, under Iran’s direction, have subverted peace in the Middle East. As Shillman Fellow Daniel Greenfield notes in his insightful introduction, this pamphlet “tells us why we should reject the “Blame Israel First” narrative that has so thoroughly saturated the mainstream media… It confronts the myth of Palestinian victimhood… and it delivers a rousing restatement of the true history of the hate that led us to all this.” America should be Israel’s protector. Instead, as David Horowitz notes, under the leadership of Barack Obama, it has become its prosecutor.

    “In this struggle for survival, we have no interest in keeping even a proportion of the city’s population alive.”During the famed 900-day siege of Leningrad, the German High Command deliberately planned to eradicate the city’s population through starvation. Viewing the Slavs as sub-human, Hitler embarked on a vicious program of ethnic cleansing. By the time the siege ended in January 1944, almost a million people had died. Those who survived would be marked permanently by what they endured as the city descended into chaos.In Leningrad, military historian Michael Jones chronicles the human story of this epic siege. Drawing on newly available eyewitness accounts and diaries, he reveals the true horrors of the ordeal—including stories long-suppressed by the Soviets of looting, criminal gangs, and cannibalism. But he also shows the immense psychological resources on which the citizens of Leningrad drew to survive against desperate odds. At the height of the siege, for instance, an extraordinary live performance of Shostakovich’s Seventh Symphony profoundly strengthened the city’s will to resist.A riveting account of one of the most harrowing sieges of world history, Leningrad also portrays the astonishing power of the human will in the face of even the direst catastrophe.

    Purchasers are entitled to a free trial membership in the General Books Club where they can select from more than a million books without charge. Subjects: Astronomy; History / General; Juvenile Nonfiction / Science

    Overy's engrossing book provides extensive details of teh slaughter, brutality, bitterness and destruction on the massive front from the White Sea to the flank of Asia.--Chicago Tribune The Russian war effort to defeat invading Axis powers, an effort that assembled the largest military force in recorded history and that cost the lives of more than 25 million Soviet soldiers and civilians, was the decisive factor for securing an Allied victory. Now with access to the wealth of film archives and interview material from Russia used to produce the ten-hour television documentary Russia's War, Richard Overy tackles the many persuasive questions surrounding this conflict. Was Stalin a military genius? Was the defense of Mother Russia a product of something greater than numbers of tanks and planes--of something deep within the Russian soul?

    But in the Soviet Union, where the ruling elites embraced, patronized, and even fetishized science like never before, scientists lived their lives on a knife edge. The Soviet Union had the best-funded scientific establishment in history. Scientists were elevated as popular heroes and lavished with awards and privileges. But if their ideas or their field of study lost favor with the elites, they could be exiled, imprisoned, or murdered. And yet they persisted, making major contributions to 20th century science.Stalin and the Scientists tells the story of the many gifted scientists who worked in Russia from the years leading up to the Revolution through the death of the “Great Scientist” himself, Joseph Stalin. It weaves together the stories of scientists, politicians, and ideologues into an intimate and sometimes horrifying portrait of a state determined to remake the world. They often wreaked great harm. Stalin was himself an amateur botanist, and by falling under the sway of dangerous charlatans like Trofim Lysenko (who denied the existence of genes), and by relying on antiquated ideas of biology, he not only destroyed the lives of hundreds of brilliant scientists, he caused the death of millions through famine.But from atomic physics to management theory, and from radiation biology to neuroscience and psychology, these Soviet experts also made breakthroughs that forever changed agriculture, education, and medicine. A masterful book that deepens our understanding of Russian history, Stalin and the Scientists is a great achievement of research and storytelling, and a gripping look at what happens when science falls prey to politics.

    Monte Carlo. The ultimate race in the Formula One calendar.When you think of Formula One, you think of Monaco. Once a year, yachts jam the harbour, celebrities fill the stands and luxury sports cars litter the streets as of thousands of people gather from across the world to watch the greatest, and one of the oldest, races in motorsport.Monaco is glamorous, prestigious and seductive. But for the drivers, it is the most demanding race of the year. The narrow streets, tight corners and sharp elevations make it the ultimate test of driving skill. It is physically draining and mentally exhausting.Proposed today, the race would not exist but it remains the jewel in the crown for every Formula One driver. There is simply no other race like it.Win at Monaco and your name is etched in history. You will join the likes of Graham Hill, Jackie Stewart, Ayrton Senna, Alain Prost, Michael Schumacher and Lewis Hamilton.With exclusive interviews and insight from drivers and a wealth of F1 insiders, award-winning sportswriter Malcolm Folley goes behind the scenes to discover what it's really like to drive and live and breathe this iconic circuit. He reveals along the way a unique and definitive portrait of the circuit, and recreates in thrilling detail its most extraordinary weekend, when only three cars finished.

    Perfect for readers of Max Hastings, Martin Middlebrook and Tim Cook. By 1915, the Western Front had descended into deadlock. Near the town of Ypres, soldiers from Canada, Britain, India, France, Belgium, the French Colonies and Germany sat in long winding trenches facing each other. German commanders sought to break through the Allied lines by using a new weapon: chlorine gas. At five o’clock on 22nd April 1915, German troops opened the valves on their deadly steel cylinders and chemical warfare entered the First World War. As the thick, yellow-green cloud of smoke was carried by the wind into Allied trenches it overcame all those who breathed in its poisonous vapours. By the end of the Second Battle of Ypres, thousands of men had been killed and even more were injured as a result of gas. J. McWilliams and R. J. Steel uncover this horrifying battle from beginning to end and explore what it was like the for the French Algerians who first witnessed the gas clouds approaching them, how the Canadians stubbornly refused to retreat in the face of gas, what the British and Indians hoped to achieve with their tragic counterattacks, and ultimately why the German offensive failed. Gas! The Battle for Ypres, 1915 discusses the course of the battle, not just from the perspective of generals, but also drawing information from the accounts of field commanders and men who were there in the trenches witnessing these terrifying events first-hand.

     You surely have heard something about the Korean War. Or the Forgotten War as some call it. But do you really know all that happened? Have you heard the personal stories from the people who actually saw or did the fighting? If you haven't, you are in for a treat. While the war was among the shortest in history, it left an invisible mark - a divided Korea. And there's a lot that led to that. It wasn't just about the UN and South Korea fighting against North Korea, China, and the Soviet Union. You will: * Learn what UN soldiers did with Chinese corpses when it got cold. * Understand Japan's role in facilitating the war. * Know the real reason China got into the war despite being very scared of America. * Know why America got stung by underequipped and underskilled Chinese fighters * Learn why Truman was saved from impeachment for firing MacAurthor. * Know why America backed an undemocratic South Korean president There is a lot more you will learn in this book. Just click the download button to start reading.