As in the earlier editions, the text contains extensive references to both the primary and review literature and provides examples of data and reactions that illustrate and document the generalizations. While the text assumes completion of an introductory course in organic chemistry, it reviews the fundamental concepts for each topic that is discussed.The two-part fifth edition has been substantially revised and reorganized for greater clarity. Among the changes: Updated material reflecting advances in the field since 2001's Fourth Edition, especially in computational chemistry; A companion Web site provides digital models for study of structure, reaction and selectivity; Solutions to the exercises provided to instructors online.The material in Part A is organized on the basis of fundamental structural topics such as structure, stereochemistry, conformation and aromaticity and basic mechanistic types, including nucleophilic substitution, addition reactions, carbonyl chemistry, aromatic substitution and free radical reactions. Together with Part B: Reaction and Synthesis, the two volumes are intended to provide the advanced undergraduate or beginning graduate student in chemistry with a sufficient foundation to comprehend and use the research literature in organic chemistry.

    The text is divided into five chapters that address the fundamentals of group theory, qualitative aspects of quantum mechanics, vibrational spectroscopy, molecular orbital theory, and electronic spectroscopy. To make the exposition clear and meaningful, each new concept is applied or illustrated with experimental results as quickly as possible. In addition, each chapter features a large number of relevant problems through which students can test their understanding of text material. These problems are an integral part of the text and sometimes introduce new material. Solutions to the problems (often accompanied by detailed explanations) can be found in an appendix.Carefully written to provide a solid foundation in spectroscopic analysis, the book devotes significant attention to the interpretation and significance of vibrational and electronic spectra, including good introductory material on Raman and photo-electron spectroscopy, vibronic analysis, and transition metal complexes. Moreover, many of the concepts presented clearly here can be easily extended to studies in other fields of chemistry. Also included are numerous helpful figures and line drawings illustrating important concepts.

    Intended for professionals and students, this work offers guidance in the designing and operating of processing units.

    A New Certificate Chemistry is known throughout the world as an invaluable resource for school chemistry courses, both in the classroom and in the laboratory.